Senin, 17/10/2011
| Final score | Estadio San Mames | |
| Athletic Bilbao | 0- 0 | Osasuna |
Minggu, 16/10/2011
| Final score | Estadio Ramon Sanchez Pizjuan | |
| Sevilla | 2 - 1 | Sporting Gijon |
| Manu del Moral (15) | David Barral (64) | |
| Martin Caceres (56) | ||
| Final score | Ciudad de Valencia | |
| Levante | 3 - 0 | Malaga |
| Juanlu (30) | ||
| Arouna Kone (41) | ||
| Jose Barkero (14) | ||
| Final score | Estadio La Romareda | |
| Real Zaragoza | 2 - 0 | Real Sociedad |
| Helder Postiga (49) | ||
| Helder Postiga (10) | ||
| Final score | Teresa Rivero | |
| Rayo Vallecano | 0 - 1 | Espanyol |
| Koffi Ndri Romaric (56) | ||
| Final score | Los Carmenes | |
| Granada | 0 - 0 | Atletico Madrid |
| Final score | Estadio Camp Nou | |
| Barcelona | 3 - 0 | Racing Santander |
| Lionel Messi (68) | ||
| Lionel Messi (11) | ||
| Xavi Hernandez (27) | ||
Sabtu, 15/10/2011
| Final score | Santiago Bernabeu | ||
| Real Madrid | 4 - 1 | Real Betis | |
| Kaka (59) | Jorge Molina (69) | ||
| Gonzalo Higuain (73) | |||
| Gonzalo Higuain (70) | |||
| Gonzalo Higuain (46) | |||
| Final score | Alfonso Perez | ||
| Getafe | 0 - 0 | Villarreal | |
| Final score | ONO Estadi | ||
| Mallorca | 1 - 1 | Valencia | |
| Tomer Hemed (90) | Adil Rami (38) | ||
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